Surface Functionalization Utilizing Mesoporous Silica Nanoparticles for Enhanced Evanescent-Field Mid-Infrared Waveguide Gas Sensing

نویسندگان

چکیده

This work focuses on the development of nanoparticle-based layer-by-layer (LbL) coatings for enhancing detection sensitivity and selectivity volatile organic compounds (VOCs) using on-chip mid-infrared (MIR) waveguides (WGs). First, we demonstrate construction conformal polymer/mesoporous silica nanoparticles (MSNs) surface Si-based WGs LbL technique evaluate coating deposition conditions, such as pH substrate withdrawal speed, thickness homogeneity assemblies. We then use modified to achieve enhanced polar compounds, ethanol, versus non-polar ones, methane, in MIR region. In addition, density functional theory calculations, show that an improvement sensing performance is achieved due preferential adsorption ethanol molecules within MSNs vicinity WG evanescent field.

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ژورنال

عنوان ژورنال: Coatings

سال: 2021

ISSN: ['2079-6412']

DOI: https://doi.org/10.3390/coatings11020118